EVIDENCE OF IONIC ADSORPTION ON C(12)E(6) NONIONIC MICELLAR SOLUTIONS

被引:1
作者
BRIGANTI, G
BONINCONTRO, A
机构
[1] Dipartimento di Fisica, Università La Sapienza, Roma, 00185
来源
NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS | 1994年 / 16卷 / 09期
关键词
D O I
10.1007/BF02462049
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In this paper we present conductivity measurements on different concentrations of C(12)E(6) non-ionic surfactant solutions as a function of temperature and buffer ionic strength. The experimental data were analysed by means of Looyenga equation. The isothermal slopes of the linearized Looyenga equation depend on the ionic strength, showing saturation effect. Our results indicate that one of the basic hypotheses of the mixture equations is not fulfilled. Adsorption of light ions at micellar interface is necessary to justify the experimental data. Then for non-ionic surfactant solutions the ion adsorption prevents any explicit computation of the micellar hydrated volume.
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收藏
页码:1613 / 1618
页数:6
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