ROLE OF COMPLEXING AGENTS IN ELECTRODEPOSITION OF BI-SR-CA-CU FILMS

被引：8

作者：

PAWAR, SH

MUJAWAR, HA

机构：

[1] Energy Studies Laboratory, Department of Physics, Shivaji University, Kolhapur

来源：

MATERIALS LETTERS | 1991年 / 10卷 / 7-8期

关键词：

D O I：

10.1016/0167-577X(91)90152-V

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrodeposition of Bi-Sr-Ca-Cu films from aqueous acidic and alkaline medium baths was carried out onto fluorine-doped tin-oxide (FTO) coated MgO substrates. The complex baths were formed with sodium citrate, ethylenediaminetetra-acetic acid (EDTA), tartaric acid, and sodium nitrate. The deposition potentials were found to depend on complexing agents. For the Bi-Sr-Ca-Cu system, the role of complexing agents on the cathodic polarization behaviour, cathodic current density, thickness of the film, and microstructural properties was studied. After proper oxidation, the films showed superconductivity with onset and zero-resistivity temperatures of 95 and 76 K respectively.

引用

页码：355 / 360

页数：6

共 7 条

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