1,2-BIS(AZACROWN)ETHANES - EFFECT OF BRIDGE SUBSTITUTION AND RING SIZE ON FORMATION OF SANDWICH COMPLEXES WITH SODIUM AND POTASSIUM-IONS

被引:6
作者
BELOHRADSKY, M
HOLY, P
KOUDELKA, J
ZAVADA, J
机构
关键词
D O I
10.1135/cccc19930153
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title problem was investigated potentiometrically using four homologous series of bis(azacrown)s I - IV. A surprisingly large destabilizing effect of bridge substituent was found in the intramolecular sandwich complex formation and ascribed to symmetry violation.
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页码:153 / 158
页数:6
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