THE GROWTH AND ELECTROCHEMICAL PROPERTIES OF V6O13 FLASH-EVAPORATED FILMS

被引：19

作者：

GORENSTEIN, A

KHELFA, A

GUESDON, JP

NAZRI, GA

HUSSAIN, OM

IVANOV, I

机构：

[1] GM CORP, CTR RES & DEV, DEPT PHYS CHEM, WARREN, MI 48090 USA

[2] SRI VENKATESWARA UNIV, THIN FILM LAB, TIRUPATI 517502, ANDHRA PRADESH, INDIA

[3] UNIV ESTADUAL CAMPINAS, INST PHYS, BR-6165 CAMPINAS, BRAZIL

来源：

SOLID STATE IONICS | 1995年 / 76卷 / 1-2期

关键词：

THIN-FILM; FLASH-EVAPORATION; LITHIUM INTERCALATION; VANADIUM OXIDE;

D O I：

10.1016/0167-2738(94)00237-M

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The growth of V6O13 films is reported for the first time. We have investigated the structural, optical, and electrical properties of flash-evaporated polycrystalline films and how these properties are affected by different thin-film preparation conditions. The highest quality films were grown on silicon substrate maintained at 250 degrees C. Microbatteries fabricated with cathode formed at moderate temperature exhibit a monotonous discharge voltage curve, indicating that the material remains in a single phase even for high degree of lithium intercalation. For cathode films prepared at 250 degrees C, lithium diffusivity is 10(-13) cm(2) s(-1) in LixV6O13.

引用

页码：133 / 141

页数：9

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