Study on preconcentration and separation of trace Pd(II) and Pt(IV) with silica gel bonded by aminopropyl-benzoylazo-1-(2-pyridylazo)-2-naphthol

被引:16
作者
Liu, F [1 ]
Li, KA [1 ]
Wu, YS [1 ]
Wang, X [1 ]
Tong, SY [1 ]
机构
[1] BEIJING UNIV,DEPT CHEM,BEIJING 100871,PEOPLES R CHINA
关键词
D O I
10.1006/mchj.1995.1098
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper reports on preconcentration and separation of trace Pd(II) and Pt(IV) with silica gel bonded by aminopropyl-benzoylazo-1-(2-pyridylazo)-2-naphthol (ABPN . SG). ABPN . SG is stable in solution between 6 mol/liter HCl and pH 9.0. The maximum adsorptive capacity of Pd(II) on ABPN . SG is 96 mu mol/g. After preconcentration and separation using an ABPN . SG column, Pd(II) and Pt(IV) of ppb level in artificial water samples can be measured by spectrophotometry. (C) 1995 Academic Press, Inc.
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页码:274 / 281
页数:8
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