A HIGHLY OXYGENATED GERMACRANE FROM ASPILIA-EENII AND CONSTITUENTS FROM OTHER ASPILIA SPECIES

被引：12

作者：

GANZER, U ^{[1
]}

JAKUPOVIC, J ^{[1
]}

BOHLMANN, F ^{[1
]}

KING, RM ^{[1
]}

机构：

[1] SMITHSONIAN INST, DEPT BOT, WASHINGTON, DC 20560 USA

来源：

PHYTOCHEMISTRY | 1992年 / 31卷 / 01期

关键词：

ASPILIA SP; COMPOSITAE; KAURANE DERIVATIVES; GERMACRANE DERIVATIVE;

D O I：

10.1016/0031-9422(91)83037-L

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Investigation of 11 Aspilia species afforded several known kaurane derivatives and other diterpenes. From A. eenii a highly oxygenated germacrane bisepoxide was isolated. Comparison of the H-1 NMR data with those of several germacrane derivatives from Senecio and Ligularia species, spin decoupling and NOED led to corrections of the structures of several compounds.

引用

收藏

页码：209 / 212

页数：4

相关论文

共 15 条

[1] NATURALLY-OCCURRING TERPENE DERIVATIVES .311. SESQUITERPENES FROM KLEINIA SPECIES [J].

BOHLMANN, F ;

AHMED, M ;

JAKUPOVIC, J ;

JEFFREY, C .

PHYTOCHEMISTRY, 1981, 20 (02) :251-256

[2] NATURALLY-OCCURRING TERPENE DERIVATIVES .437. 4 OPLOPANONE AND BISABOLONE DERIVATIVES FROM RUGELIA-NUDICAULIS [J].

BOHLMANN, F ;

GUPTA, RK ;

JAKUPOVIC, J ;

KING, RM ;

ROBINSON, H .

PHYTOCHEMISTRY, 1982, 21 (07) :1665-1668

[3] DITERPENE LACTONES AND OTHER CONSTITUENTS FROM WEDELIA AND ASPILIA SPECIES [J].

BOHLMANN, F ;

GERKE, T ;

JAKUPOVIC, J ;

BORTHAKUR, N ;

KING, RM ;

ROBINSON, H .

PHYTOCHEMISTRY, 1984, 23 (08) :1673-1676

[4] NATURALLY OCCURRING TERPENE DERIVATIVES .218. NEW GERMACRENE DERIVATIVES FROM SENECIO SPECIES [J].

BOHLMANN, F ;

ZIESCHE, J .

PHYTOCHEMISTRY, 1979, 18 (09) :1489-1493

[5]

BOHLMANN F, 1983, LIEBIGS ANN CHEM, P962

[6]

BOHLMANN F, 1983, LIEBIGS ANN CHEM, P1257

[7] EREMOPHILANE DERIVATIVES AND OTHER CONSTITUENTS FROM SENECIO SPECIES [J].

BOHLMANN, F ;

ZDERO, C ;

JAKUPOVIC, J ;

MISRA, LN ;

BANERJEE, S ;

SINGH, P ;

BARUAH, RN ;

METWALLY, MA ;

SCHMEDAHIRSCHMANN, G ;

VINCENT, LPD ;

KING, RM ;

ROBINSON, H .

PHYTOCHEMISTRY, 1985, 24 (06) :1249-1261

[8] NATURALLY-OCCURRING TERPENE DERIVATIVES .148. NEW EREMOPHILENES FROM SOUTH-AFRICAN SPECIES OF SENECIO [J].

BOHLMANN, F ;

ZDERO, C .

PHYTOCHEMISTRY, 1978, 17 (08) :1337-1341

[9] NATURALLY-OCCURRING TERPENE DERIVATIVES .299. SESQUITERPENES FROM 3 SENECIO SPECIES [J].

BOHLMANN, F ;

ZIESCHE, J .

PHYTOCHEMISTRY, 1981, 20 (03) :469-472

[10] NATURALLY OCCURRING TERPENE DERIVATIVES .98. CONSTITUENTS OF GENUS LIGULARIA [J].

BOHLMANN, F ;

EHLERS, D ;

ZDERO, C ;

GRENZ, M .

CHEMISCHE BERICHTE-RECUEIL, 1977, 110 (07) :2640-2648