EXPERIMENTAL-ANALYSIS OF THE ANTI-BONDING TRIMETAL CHARACTER OF THE HOMO IN THE PARAMAGNETIC FISCHER-PALM NI3(ETA-5-C5H5)3(MU-3-CO)2 CLUSTER - SYNTHESIS AND STEREOCHEMICAL CHARACTERIZATION OF THE ELECTRONICALLY EQUIVALENT [(ETA-5-C5ME5)CONI2(ETA5-C5H5)2(MU-3-CO)2]-MONOANION AND NEUTRAL NI3(ETA-5-C5ME5)3(MU-3-CO)2 ANALOG AND OF THE [NI3(ETA-5-C5H5)3(MU-3-CO)2]-MONOANIONTR

被引：59

作者：

MAJ, JJ ^{[1
]}

RAE, AD ^{[1
]}

DAHL, LF ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1982年 / 104卷 / 11期

关键词：

D O I：

10.1021/ja00375a019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：3054 / 3063

页数：10

共 63 条

[1] SYNTHETIC ANALOGS OF ACTIVE-SITES OF IRON-SULFUR PROTEINS .2. SYNTHESIS AND STRUCTURE OF TETRA[MERCAPTO-MU3-SULFIDO-IRON] CLUSTERS, [FE4S4(SR)4]2- [J].

AVERILL, BA ;

HERSKOVITZ, T ;

HOLM, RH ;

IBERS, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (11) :3523-3534

[2] HOMOPOLYATOMIC ANIONS AND CONFIGURATIONAL QUESTIONS - SYNTHESIS AND STRUCTURE OF NONAGERMANIDE(2-) IONS AND NONAGERMANIDE(4-) IONS, GE92- AND GE94-1 [J].

BELIN, CHE ;

CORBETT, JD ;

CISAR, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (22) :7163-7169

[3] CRYSTAL-STRUCTURE OF [(C2H5)4N]3[FE4S4(SCH2PH)4], A REDUCED FERREDOXIN SITE ANALOG WITH A NONTETRAGONAL FE4S4 CORE STRUCTURE IN THE SOLID-STATE [J].

BERG, JM ;

HODGSON, KO ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (16) :4586-4593

[4] INORGANIC DERIVATIVES OF IRON-SULFIDE-THIOLATE DIMERS AND TETRAMERS - STRUCTURES OF TETRACHLORO-MU-DISULFIDO-DIFERRATE(III) AND TETRAKIS(CHLORO-MU-3-SULFIDO-IRON) DIANIONS [J].

BOBRIK, MA ;

HODGSON, KO ;

HOLM, RH .

INORGANIC CHEMISTRY, 1977, 16 (08) :1851-1858

[5] STRUCTURAL-ANALYSIS OF (PENTAMETHYLCYCLOPENTADIENYL)COBALT(I) DICARBONYL - EVIDENCE FOR AN ELECTRONICALLY INDUCED DISTORTION OF THE CYCLOPENTADIENYL RING DUE TO ITS INTERACTION WITH A PLANAR CO(CO)2 FRAGMENT [J].

BYERS, LR ;

DAHL, LF .

INORGANIC CHEMISTRY, 1980, 19 (02) :277-284

[6] SYNTHESIS AND STEREOCHEMICAL ANALYSIS OF THE TRIANGULAR COBALT-DINICKEL CLUSTERS (ETA-5-C5H5-NMEN)CONI2(ETA-5-C5H5)2(MU3-CO)2 (WHERE N= 0, 1, 5) - DIRECT EVIDENCE FOR THE ANTI-BONDING TRIMETAL CHARACTER OF THE UNPAIRED ELECTRON IN THE FISCHER-PALM NI3(ETA-5-C5H5)3(MU-3-CO)2 AND RESULTING GEOMETRICAL EFFECTS UPON FORMAL OXIDATION BY REPLACEMENT OF A NICKEL WITH A COBALT ATOM [J].

BYERS, LR ;

UCHTMAN, VA ;

DAHL, LF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :1942-1951

[7] SYNTHETIC TETRANUCLEAR IRON-SULFUR COMPLEX WITH IONIZED SIDE-CHAINS - CRYSTAL-STRUCTURE OF (FE4S4(S(CH2)2COO)4)6-.(NA5.N(C4H9)4)6+.5C5H9NO [J].

CARRELL, HL ;

GLUSKER, JP ;

JOB, R ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (11) :3683-3690

[8]

CHU CTW, J AM CHEM SOC

[9] SYNTHESIS, STEREOCHEMISTRY, AND BONDING OF THE COBALT COBALT MULTIPLE-BONDED (PENTAMETHYLCYCLOPENTADIENYL) CARBONYL DIMERS AND CYCLOPENTADIENYLCOBALT CARBONYL DIMERS, [CO-2(ETA-5-C5R5)2(MU-CO)2]N (R = ME, N = 0, 1- - R = H, N = 1-) - A COMPARATIVE-ANALYSIS OF THE ANTI-BONDING DIMETAL NATURE OF THE UNPAIRED ELECTRON IN THE MONO-ANIONS AND ITS STRUCTURAL EFFECTS UPON OXIDATION [J].

CIRJAK, LM ;

GINSBURG, RE ;

DAHL, LF .

INORGANIC CHEMISTRY, 1982, 21 (03) :940-957

[10]

CIRJAK LM, J CHEM SOC, P470

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