SEX-PHEROMONE BIOSYNTHESIS IN MAMESTRA-BRASSICAE L (LEPIDOPTERA, NOCTUIDAE) - STEREOCHEMISTRY OF THE DELTA(11) DESATURATION

被引：18

作者：

BOLAND, W ^{[1
]}

FROSSL, C ^{[1
]}

SCHOTTLER, M ^{[1
]}

TOTH, M ^{[1
]}

机构：

[1] HUNGARIAN ACAD SCI,INST PLANT PROTECT,H-1525 BUDAPEST,HUNGARY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 14期

关键词：

D O I：

10.1039/c39930001155

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(11S,12R)-and (11R,12S)-[H-2(14)]palmitic acids 1 are converted in the pheromone gland of the moth Mamestra brassicae into the [H-2(11)]- or [H-2(13)]-hexadec-11-enyl acetates 2 by a formal syn-elimination of the C(11)-H(R) and C(12)-H(R) hydrogen atoms; this characterises the unique DELTA11 desaturase from insects as closely related to the DELTA9 desaturases from mammals, plants and bacteria.

引用

页码：1155 / 1157

页数：3

共 14 条

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