NEW ACHIEVEMENT IN THE USE OF ZIRCONIUM COMPLEXES IN THE CHEMISTRY OF ORGANOALUMINUM AND MAGNESIUM COMPOUNDS

被引:54
作者
DZHEMILEV, UM
机构
[1] Institute of Petrochemistry and Catalysis, the Beshkortostan Academy of Sciences
关键词
D O I
10.1016/0040-4020(94)01123-H
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This paper describes some applications of a new reaction of catalytic cyclometallation of alpha-olefins, norbornenes and their derivatives, and 1,2-disubstituted acetylenes with organomagnesium and organoaluminium compounds effected by zirconium catalysts, leading to a series of five asd macrocyclic heterocycles containing magnesium and aluminium.
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页码:4333 / 4346
页数:14
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