FACE-TO-FACE METALLOCENES - THE SYNTHESIS OF A CYMANTRENE-FERROCENE TRIAD

被引：11

作者：

GRONBECK, DA ^{[1
]}

MATCHETT, SA ^{[1
]}

ROSENBLUM, M ^{[1
]}

机构：

[1] BRANDEIS UNIV,DEPT CHEM,WALTHAM,MA 02254

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)97782-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,8-diiodonaphthalene is converted through successive coupling with cyclopentadienylcopper dimethyl sulfide followed by complexation with iron and then manganese tricarbonyl to the trimetallic complex 7 in which adjacent cyclopentadienylmanganese tricarbonyl and ferrocene units are held face-to-face. © 1990.

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页码：4977 / 4980

页数：4

相关论文

共 21 条

[1] PREPARATION AND PROPERTIES OF STACKED OLIGOMERIC AND POLYMERIC METALLOCENES [J].

ARNOLD, R ;

MATCHETT, SA ;

ROSENBLUM, M .

ORGANOMETALLICS, 1988, 7 (11) :2261-2266

[2] TRIPLE-DECKED SANDWICH COMPOUNDS - PLANAR C2B3H 4/5 CYCLOCARBORANE LIGANDS ANALOGOUS TO C5H/5 [J].

BEER, DC ;

MILLER, VR ;

SNEDDON, LG ;

GRIMES, RN ;

MATHEW, M ;

PALENIK, GJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (09) :3046-3048

[3] BIS((PENTAMETHYLCYCLOPENTADIENYL)METAL)PENTALENES - A NEW CLASS OF HIGHLY DELOCALIZED, FUSED METALLOCENES [J].

BUNEL, EE ;

VALLE, L ;

JONES, NL ;

CARROLL, PJ ;

BARRA, C ;

GONZALEZ, M ;

MUNOZ, N ;

VISCONTI, G ;

AIZMAN, A ;

MANRIQUEZ, JM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (19) :6596-6598

[4] EXTENDED POLYMETALLIC SANDWICH COMPOUNDS [J].

BURDETT, JK ;

CANADELL, E .

ORGANOMETALLICS, 1985, 4 (05) :805-815

[5] CHEMISTRY OF BIS(ETA-6-NAPHTHALENE)CHROMIUM LIGAND-EXCHANGE REACTIONS - SYNTHESIS AND CHARACTERIZATION OF POLY[(MU-ETA-6,ETA-6-NAPHTHALENE)CHROMIUM] [J].

BUSH, BF ;

LAGOWSKI, JJ .

ORGANOMETALLICS, 1988, 7 (09) :1945-1948

[6] A SUPERPHANE OF CYCLOBUTADIENE CAPPED BY CYCLOPENTADIENYLCOBALT [J].

GLEITER, R ;

KARCHER, M ;

ZIEGLER, ML ;

NUBER, B .

TETRAHEDRON LETTERS, 1987, 28 (02) :195-198

[7]

GOGAN NJ, 1986, J ORGANOMET CHEM, V301, pC31

[8] COFACIAL CYCLOPENTADIENES - SYNTHESIS AND REACTIONS OF 1,8-BIS(CYCLOPENTADIENYL)NAPHTHALENE [J].

GRONBECK, DA ;

MATCHETT, SA ;

ROSENBLUM, M .

TETRAHEDRON LETTERS, 1989, 30 (22) :2881-2884

[9]

HERBERICH GE, 1989, J ORGANOMET CHEM, V53, P372

[10] METALLOCENOPHANES .5. MULTIDECKER METALLOCENOPHANES [J].

HOPF, H ;

DANNHEIM, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (05) :701-701