SYNTHESIS OF 1,3-DIENES BEARING BOTH ELECTRON-DONOR AND ACCEPTOR SUBSTITUENTS

被引：22

作者：

MOREAU, P ^{[1
]}

ALNEIRABEYEH, M ^{[1
]}

GUILLAUMET, G ^{[1
]}

COUDERT, G ^{[1
]}

机构：

[1] UNIV ORLEANS,CNRS,CHIM BIOORGAN & ANALYT LAB,BP 6759,F-45067 ORLEANS 2,FRANCE

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 40期

关键词：

1,4-BENZODIOXIN; ALLYLIC BENZODIOXINIC ALCOHOLS; CLAISEN REARRANGEMENTS; 2-ALKYLIDENE-1,4-BENZODIOXANS; 1,3-DIENES;

D O I：

10.1016/0040-4039(91)80074-G

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Allylic benzodioxinic alcohols were prepared from 1,4-benzodioxin and then submitted to the orthoester Claisen rearrangement and Eschenmoser procedure leading to 3-substituted-2-alkylidene-1,4-benzodioxans. Di-and trisubstituted 1,3-dienes bearing both electron-donor and acceptor substituents were obtained in good yields from these compounds.

引用

页码：5525 / 5528

页数：4

共 8 条

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