PALLADIUM-CATALYZED NUCLEOPHILIC-SUBSTITUTION OF NAPHTHYLMETHYL AND 1-NAPHTHYLETHYL ESTERS

被引：68

作者：

LEGROS, JY

FIAUD, JC

机构：

[1] Laboratoire de Synthése Asymeétrique Associé au C.N.R.S. Bâtiment 420, Université de Paris-Sud

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

PALLADIUM(0) PHOSPHINE CATALYST; NAPHTHYLMETHYL AND 1-NAPHTHYLETHYL ESTERS; SUBSTITUTION; SODIUM DIMETHYL MALONATE;

D O I：

10.1016/S0040-4039(00)92227-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Sodium dimethyl malonate reacted with naphthylmethyl and 1-naphthylethyl alcohol derivatives in DMF at 20-80-degrees-C, under palladium(0) / phosphine catalysis. to give the substitution products dimethyl naphthylmethyl- and 1-naphthylethylmalonates. respectively, in good (75-83%) yield.

引用

页码：2509 / 2510

页数：2