LIBA4[MO2N7].BACL2 - DIMERIC ANIONS [MO2N7]9- BY CONDENSATION REACTION OF BA3[MON4] IN LICL MELTS

被引：19

作者：

GUDAT, A ^{[1
]}

KNIEP, R ^{[1
]}

MAIER, J ^{[1
]}

机构：

[1] TH DARMSTADT,EDUARD ZINTL INST,W-6100 DARMSTADT,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1992年 / 47卷 / 10期

关键词：

NITRIDOMOLYBDATE(VI); DIMERIC ANIONS; PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1515/znb-1992-1004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pale yellow crystals of LiBa4[Mo2N7].BaCl2 (Monoclinic, P2(1)/m; a = 1113.5(3), b = 605.8(1), c = 1122.7(3) pm; beta = 95.65(2)-degrees; Z = 2) were grown from the melt (LiCl/Ba3[MoN4], molar ratio 3:1, T(max) = 1050-degrees-C) by cooling (5-degrees-C/h). The crystal structure contains dimeric units [Mo2N7]9- (eclipsed conformation; N-Mo-N: 173.7-degrees; Mo-N(term.): 182.7(5)-186.1(8) pm; Mo - N(bridg.): 190.6(8) and 192.3(8) pm).

引用

页码：1363 / 1366

页数：4

共 12 条

[1] BECKER HJ, 1978, J CHEM RES, P167
[2] BRACKETT EB, 1963, J PHYS CHEM-US, V67, P3132
[3] BRICE JF, 1970, CR ACAD SCI C CHIM, V271, P825
[4] THE CRYSTAL-STRUCTURES OF THE ISOTYPIC COMPOUNDS BA3[MON4] AND BA3[WN4]
GUDAT, A
HOHN, P
KNIEP, R
RABENAU, A
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (05): : 566 - 572
[5] GUDAT A, 1990, Z NATURFORSCH B, V45, P111
[6] GUDAT A, 1990, THESIS U DUSSELDORF
[7] HOHN P, THESIS TH DARMSTADT
[8] LEVINSH AF, 1938, Z PHYS CHEM B LPZ, V40, P146
[9] CRYSTAL-STRUCTURES OF LIALCL4 AND NAALCL4 AS A FUNCTION OF TEMPERATURE
PERENTHALER, E
SCHULZ, H
RABENAU, A
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 491 (08): : 259 - 265
[10] Pope M.T., 1983, HETEROPOLY ISOPOLY O

← 1 2 →