NOVEL NETWORKS OF UNUSUALLY COORDINATED SILVER(I) CATIONS - THE WAFER-LIKE STRUCTURE OF [AG(PYZ)(2)][AG-2(PYZ)(5)](PF6)(3)CENTER-DOT-2G AND THE SIMPLE CUBIC FRAME OF [AG(PYZ)(3)](SBF6)

被引：288

作者：

CARLUCCI, L ^{[1
]}

CIANI, G ^{[1
]}

PROSERPIO, DM ^{[1
]}

SIRONI, A ^{[1
]}

机构：

[1] CTR CNR, I-20133 MILAN, ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1995年 / 34卷 / 17期

关键词：

COORDINATION POLYMERS; COMPLEXES WITH NITROGEN LIGANDS; SOLIDS; SILVER COMPOUNDS;

D O I：

10.1002/anie.199518951

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silver salts AgPF6 and AgSbF6 react with pyrazine to give unprecedented networks of two‐ and three‐dimensional cubic units. The PF 6− derivative has a layered structure, whereas the SbF 6− derivative (shown schematically on the right) contains a simple cubic frame of the α‐polonium type. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1895 / 1898

页数：4

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