AN UNUSUAL REDUCTION OF URANYL-ION TO URANIUM(IV)

被引：18

作者：

GREIWING, H

KREBS, B

PINKERTON, AA

机构：

[1] UNIV TOLEDO,DEPT CHEM,TOLEDO,OH 43606

[2] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 234卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; URANIUM COMPLEXES; DITHIOPHOSPHORUS LIGAND COMPLEXES; DINUCLEAR COMPLEXES;

D O I：

10.1016/0020-1693(95)04612-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The isolation and structural characterization of the dimeric uranium(IV) species [U{S(2)PMe(2)}(2){O(S)PMe(2)}{mu-O(2)PMe(2)}](2) starting from UO2Cl2 . 3H(2)O and NaS(2)PMe(2) is reported. Crystal data: C26H48O6P8S10U2, M(r),= 1381.05, monoclinic, P2(1)/c, a =13.754(2), b=15.103(1), c = 11.798(1) Angstrom, beta = 101.13(1)degrees, V = 2405(1) Angstrom(3), Z = 2, lambda(Mo K alpha) = 0.70930 Angstrom, R = 0.036 for 3224 unique observed reflections. The geometry at uranium is pentagonal bipyramidal.

引用

页码：127 / 130

页数：4

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