THERMAL ELECTROCYCLIC RING-OPENING OF CYCLOBUTENES - SUBSTITUENTS WITH COMPLEMENTARY CONROTATORY PREFERENCES INDUCE HIGH STEREOSELECTIVITY

被引：21

作者：

HAYES, R ^{[1
]}

INGHAM, S ^{[1
]}

SAENGCHANTARA, ST ^{[1
]}

WALLACE, TW ^{[1
]}

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,SALFORD M5 4WT,LANCS,ENGLAND

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 25期

关键词：

D O I：

10.1016/0040-4039(91)80660-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The thermal transformation of cis-disubstituted cyclobutenes into conjugated (Z,E)-dienes is stereoselective when the electronic and, to a lesser degree, steric effects of the substituents induce complementary conrotatory preferences at the reaction termini.

引用

页码：2953 / 2954

页数：2

共 11 条

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