ENDORECEPTORS WITH CONVERGENT PHENANTHROLINE UNITS - A MOLECULAR CAVITY FOR 6 GUEST MOLECULES

被引：43

作者：

VOGTLE, F ^{[1
]}

LUER, I ^{[1
]}

BALZANI, V ^{[1
]}

ARMAROLI, N ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTMENTO CHIM,I-40126 BOLOGNA,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 10期

关键词：

D O I：

10.1002/anie.199113331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three docking sites ensure that six guests jostle in the cavity of a new endo receptor. Three phenanthroline molecules are brought into close proximity by coordination of each with a Cu(I) ion. In the FAB mass spectrometer the host complete with all six guests exists as the molecular supercomplex 1. Three bulky guest molecules are not "invited" simultaneously (R = CH3, p-C6H4CH3; R' = H) because of the limited space in the cavity.

引用

页码：1333 / 1336

页数：4

共 28 条

[1] EXCITED-STATE PROPERTIES IN SUPRAMOLECULAR SYSTEMS - LUMINESCENCE AND INTERCOMPONENT INTERACTIONS IN A 3-CATENAND AND SOME 3-CATENATES [J].