INFRARED-SPECTRA OF [N]STAFFANES

被引：10

作者：

GUDIPATI, MS

HAMROCK, SJ

BALAJI, V

MICHL, J

机构：

[1] UNIV COLORADO,DEPT CHEM & BIOCHEM,BOULDER,CO 80309

[2] UNIV TEXAS,AUSTIN,TX 78712

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 25期

关键词：

D O I：

10.1021/j100204a016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The IR spectra of the rust five oligomers of [1.1.1]propellane ([n]staffanes, n = 1-5), and some of their bridgehead-deuteriated derivatives, have been measured in argon matrix isolation. IR transition moment directions were obtained using stretched polyethylene as solvent. Assignments were based on a simple model of interacting subunits and on comparison with 3-21G HF calculations. IR peaks particularly suitable for use in the determination of orientation of the staffane moieties in supramolecular assemblies have been identified.

引用

页码：10165 / 10176

页数：12

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