POLY[ETHYNYLENE(3-NORMAL-BUTYL-2,5-THIOPHENEDIYL)-ETHYNYLENE] - A SOLUBLE POLYMER CONTAINING DIACETYLENE UNITS AND ITS CONVERSION TO A HIGHLY CROSS-LINKED ORGANIC-SOLID

被引：45

作者：

CALLSTROM, MR ^{[1
]}

NEENAN, TX ^{[1
]}

WHITESIDES, GM ^{[1
]}

机构：

[1] HARVARD UNIV, DEPT CHEM, CAMBRIDGE, MA 02138 USA

来源：

MACROMOLECULES | 1988年 / 21卷 / 12期

关键词：

Monomers--Polymerization; -; Oligomers--Solubility; Plastics--Crosslinking; Solids--Synthesis;

D O I：

10.1021/ma00190a034

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The authors report the results of a study of poly[ethynylene-(3-n-butyl-2,5-thiophenediyl)ethynylene] and related oligomers and polymers: preparation of these diacetylenic oligomers and polymers in soluble form, conversion of the oligomers to hypercross-linked organic solids with high carbon content, and characterization of these solids. It is shown that the solubility, Young's modulus and thermal stability of poly[ethynylene(3-n-butyl-2,5-thiophenediyl)-ethynylene] and related oligomers and polymers provide an attractive system for the exploration of the properties of hypercross-linked solids.

引用

页码：3528 / 3530

页数：3

共 16 条

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