PLATINUM-COMPLEX-CATALYZED DOUBLE SILYLATION OF ETHYLENE AND NORBORNENE WITH DISILANES

被引：107

作者：

HAYASHI, T ^{[1
]}

KOBAYASHI, T ^{[1
]}

KAWAMOTO, AM ^{[1
]}

YAMASHITA, H ^{[1
]}

TANAKA, M ^{[1
]}

机构：

[1] NATL CHEM LAB IND,TSUKUBA,IBARAKI 305,JAPAN

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 01期

关键词：

Disilanes - Norbornene - Platinum Phosphine Complexes - Silylation;

D O I：

10.1021/om00115a043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Double silylation of ethylene with disilanes was found to proceed in the presence of platinum phosphine complexes to give 1,2-bis(silyl)ethanes. The reactivity was enhanced by electronegative and sterically less demanding substituents on the silicon atom. The reaction of norbornene suggested cis addition of disilanes to the C═C bond. © 1990, American Chemical Society. All rights reserved.

引用

页码：280 / 281

页数：2

共 20 条

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