HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF ADSORBATES ON IONIC-CRYSTAL SURFACES

被引：39

作者：

HEIDBERG, J

KAMPSHOFF, E

KUHNEMUTH, R

SCHONEKAS, O

SUHREN, M

机构：

[1] Institut für Physikalische Chemie, Elektrochemie der Universität Hannover, D-3000 Hannover 1, Callinstr. 3-

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1990年 / 54卷

关键词：

D O I：

10.1016/0368-2048(90)80286-J

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Infrared spectra of adsorbates on ionic single crystal surfaces were measured using high resolution polarized Fourier-transform spectroscopy in transmission: CO2 on NaCl(100) and CO on NaCl(100). Spectral lines of widths less-than-or-equal-to 0.04 cm-1 were observed, the sharpest of adsorbates known. The kind of information derived in the fields of vibrations, structure, thermodynamics and dynamics on surfaces is illustrated.

引用

页码：945 / 960

页数：16

共 37 条

[1] MEASUREMENT OF THE RAYLEIGH SURFACE-PHONON DISPERSION CURVE FOR NACL(001) FROM HIGH-RESOLUTION HE TIME-OF-FLIGHT SPECTROSCOPY AND FROM KINEMATICAL FOCUSING ANGLES [J].

BENEDEK, G ;

BRUSDEYLINS, G ;

DOAK, RB ;

SKOFRONICK, JG ;

TOENNIES, JP .

PHYSICAL REVIEW B, 1983, 28 (04) :2104-2113

[2] PREDESORPTION OF CO FROM THE SODIUM CHLORIDE(100) SURFACE - STUDY BY THE COMPLEX COORDINATE METHOD [J].

BENEPHRAIM, A ;

FOLMAN, M ;

HEIDBERG, J ;

MOISEYEV, N .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (06) :3840-3846

[3] THE DETERMINATION OF MONOLAYER STRUCTURE BY INFRARED-SPECTROSCOPY - CO2 ON NACL(100) [J].

BERG, O ;

EWING, GE .

SURFACE SCIENCE, 1989, 220 (2-3) :207-229

[4] SURFACE INFRARED-SPECTROSCOPY [J].

CHABAL, YJ .

SURFACE SCIENCE REPORTS, 1988, 8 (5-7) :211-357

[5] HIGH-RESOLUTION INFRARED-SPECTROSCOPY OF ADSORBATES ON SEMICONDUCTOR SURFACES - HYDROGEN ON SI(100) AND GE(100) [J].

CHABAL, YJ .

SURFACE SCIENCE, 1986, 168 (1-3) :594-608

[6] EPITAXIAL-GROWTH OF CO ON NACL(100) STUDIED BY INFRARED-SPECTROSCOPY [J].

CHANG, HC ;

RICHARDSON, HH ;

EWING, GE .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (12) :7561-7568

[7] THE QUANTUM EFFICIENCY OF VIBRATIONALLY INDUCED DESORPTION FOR A MONOLAYER OF CO ON NACL(100) [J].

CHANG, HC ;

EWING, GE .

CHEMICAL PHYSICS, 1989, 139 (01) :55-65

[8] MODEL CALCULATION OF INFRARED-ABSORPTION BY A MONOLAYER OF CO2 ON NACL(100) [J].

CHEN, W ;

SCHAICH, WL .

SURFACE SCIENCE, 1989, 220 (2-3) :L733-L739

[9] THE OPTICAL EFFECTS OF AN ADSORBATE LAYER - D-PARAMETER DESCRIPTION OF SIMPLE-MODELS [J].

CHEN, W ;

SCHAICH, WL .

SURFACE SCIENCE, 1989, 218 (2-3) :580-602

[10] BIMOLECULAR PHOTOREACTION OF ADSORBATES - 2-HX-]H-2+X-2 (X=CL,BR) [J].

CHO, CC ;

POLANYI, JC ;

STANNERS, CD .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (01) :598-600

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