IONIC-CONDUCTION IN (PEO)NKCUXI1+X COMPLEXES

被引：6

作者：

ATCHIA, S

PETIT, JP

SANCHEZ, JY

ARMAND, M

DEROO, D

机构：

[1] Laboratoire d'Ionique et d'Electrochimie des Solides de Grenoble, I.N.P.G.-E.N.S.E.E.G., Domaine Universitaire, 38402 St Martin d'Hères Cedex

来源：

ELECTROCHIMICA ACTA | 1992年 / 37卷 / 09期

关键词：

POLYMER ELECTROLYTES; CONDUCTIVITY; COPPER(I) COMPLEX; TRANSFERENCE NUMBER;

D O I：

10.1016/0013-4686(92)80119-7

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We introduce a new family of solid polymer electrolytes where the Cu+ cation is coordinated with an anionic ligand I-, resulting in a complex carrying at least one negative charge. In the PEOnKCuxI1+x electrolyte, potassium iodide acts as a supporting electrolyte where copper cations Cu+ are carried as CuI2- complex anions. The transport of Cu+ thus occurs via a vehicular mechanism. The Conductivity of these electrolytes is around 5 x 10(-6) OMEGA--1 cm-1 at 40-degrees-C and the transference number of copper component has been found to be 0.4.

引用

页码：1599 / 1601

页数：3

共 6 条

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