A.C. POLAROGRAPHIC STUDY OF ION TRANSFER AT THE WATER NITROBENZENE INTERFACE

被引：113

作者：

OSAKAI, T ^{[1
]}

KAKUTANI, T ^{[1
]}

SENDA, M ^{[1
]}

机构：

[1] KYOTO UNIV,FAC AGR,DEPT AGR CHEM,SAKYO KU,KYOTO 606,JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1984年 / 57卷 / 02期

关键词：

POLAROGRAPHIC ANALYSIS - WATER;

D O I：

10.1246/bcsj.57.370

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The transfer of tetramethylammonium (TMA** plus ) ion across the interface between a 0. 1 mol dm** minus **3 LiCl aqueous solution and a 0. 1 mol dm** minus **3 tetrabutylammonium tetraphenylborate nitrobenzene solution was investigated by means of phase-selective a. c. polarography. In recording the a. c. polarographic current a two-electrode cell system was used and the ohmic drop due to solution resistance in the cell was compensated for by positive feedback. The ion-transfer admittance vs. potential curves were determined in the a. c. frequency range between 10 and 100 Hz and the kinetic parameters of the TMA** plus -ion transfer across the water/nitrobenzene interface were determined.

引用

页码：370 / 376

页数：7

共 19 条

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