AEROBIC EPOXIDATION OF OLEFINIC COMPOUNDS CATALYZED BY TRIS(1,3-DIKETONATO)IRON(III)

被引：99

作者：

TAKAI, T

HATA, E

YAMADA, T

MUKAIYAMA, T

机构：

[1] MITSUI PETROCHEM IND CO LTD, CHEM SYNTH LABS, YAMAGUCHI 740, JAPAN

[2] SCI UNIV TOKYO, FAC SCI, DEPT APPL CHEM, SHINJUKU KU, TOKYO 162, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1991年 / 64卷 / 08期

关键词：

D O I：

10.1246/bcsj.64.2513

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris[1,3-bis(p-methoxyphenyl)-1,3-propanedionato]iron(III) (Fe(dmp)3) was found to be an excellent catalyst for oxygenation of a number of olefinic compounds including styrene analogues and olefinic alcohols into the corresponding epoxides in good to quantitative yields with combined use of molecular oxygen and an aldehyde at room temperature.

引用

页码：2513 / 2518

页数：6

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