WETTING HYSTERESIS - EFFECTS DUE TO SHADOWING

Wetting hysteresis due to isolated surface heterogeneities is now fairly well understood but when the solid presents a population of defects, complex cooperative effects between neighbours may exist. One such effect is that of 'shadowing', in which a proportion of the flaws near the triple line, and which would otherwise contribute to hysteresis, are masked by already existing deformations to the wetting front caused by neighbouring heterogeneities. This renders them inactive and, as a result, the hysteretic wetting force is only expected to be a linear function of density for sparse populations. Theoretical predictions are compared with experimental results obtained with model heterogeneous surfaces consisting of overhead projector transparencies bestrewn with circular ink spots - the defects. Agreement is found to be satisfactory when intrinsic angles on both the homogeneous solid and the flaws are finite, whereas the concordance is less satisfactory when the contact angle of the liquid on the homogeneous solid is zero.