EXPERIMENTAL INVESTIGATION OF SYNTHESIS GAS SOLUBILITY IN FISCHER-TROPSCH REACTOR SLURRY

被引:9
作者
HUANG, SH
LIN, HM
CHAO, KC
机构
[1] Purdue Univ, West Lafayette, IN, USA, Purdue Univ, West Lafayette, IN, USA
关键词
CARBON MONOXIDE - CHEMICAL EQUIPMENT - Reactors - CHEMICAL REACTIONS - Fischer-Tropsch Synthesis - HYDROGEN - PARAFFINS;
D O I
10.1016/0378-3812(87)85019-7
中图分类号
O414.1 [热力学];
学科分类号
摘要
A semi-flow apparatus has been designed and constructed for investigation of the phase equilibrium behavior of synthesis gas and products in a Fischer-Tropsch slurry reactor. The apparatus provides contact for a flowing gas stream with a stationary liquid and is suited for the determination of gas solubility in a molten wax of high melting point. To verify attainment of equilibrium, the new apparatus has been tested with a mixture of carbon dioxide and toluene. The test data agree well with the experimental results of Ng and Robinson from a static apparatus. Measurement has been completed for the solubility of hydrogen and of carbon monoxide in n-eicosane, n-octacosane, and in n-hexatriacontane at three temperatures (100, 200, and 300 degree C) and five pressures (10, 20, 30, 40 and 50 atm). Solubility of synthesis gas mixtures of H//2 and CO in n-octacosane was also determined at three gas temperatures (200 and 300 degree C) for each gas mixture.
引用
收藏
页码:141 / 148
页数:8
相关论文
共 9 条