THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(2,2'-6',2''-TERPYRIDINE)MAGNESIUM PERCHLORATE MONOHYDRATE

被引：19

作者：

CONSTABLE, EC ^{[1
]}

HEALY, J ^{[1
]}

DREW, MGB ^{[1
]}

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)86050-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Mg(terpy)2][ClO4]2.H2O (terpy = 2,2':6',2"-terpyridine) may be prepared by the direct reaction of magnesium perchlorate with 2,2':6',2"-terpyridine. The magnesium is in a pseudo-octahedral environment very similar to that observed in transition metal bis-(2,2':6',2"-terpyridine) complexes. Crystallographic data: space group I4(1)/a, a = 12.531(13), c = 40.52(4) angstrom, V = 2912 angstrom 3, Z = 8.

引用

页码：1883 / 1887

页数：5

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