SYNTHESIS AND STRUCTURE OF THE 1ST ALKYL-BRIDGED DOUBLE LADDER - [R(CL)SN(CH2)3SN(CL)R]O)4 (R = ME3SICH2)

被引：45

作者：

DAKTERNIEKS, D ^{[1
]}

JURKSCHAT, K ^{[1
]}

SCHOLLMEYER, D ^{[1
]}

WU, H ^{[1
]}

机构：

[1] JOHANNES GUTENBERG UNIV,INST ORGAN CHEM,W-6500 MAINZ,GERMANY

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1021/om00022a060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of ((t)Bu2SnO)3 with R(Cl2)Sn(CH2)3-Sn(Cl2)R (R = Me3SiCH2) gives an alkyl-bridged double ladder {[R(Cl)Sn(CH2)3Sn(Cl)R]O}4 which has been characterized in the solid state by X-ray crystallography and in solution by multinuclear NMR spectroscopy. The compound consists of two ladder-type layers which are bridged by four propyl chains. The structure observed in the solid state is retained in solution.

引用

页码：4121 / 4123

页数：3

共 7 条

[1] ASYMMETRIC DISTANNOXANE DIMERS
GROSS, DC
[J]. INORGANIC CHEMISTRY, 1989, 28 (12) : 2355 - 2359
[2] MOSSBAUER RECOIL-FREE FRACTION AND STRUCTURE .2. DI-MU-3-OXO-BIS-(MU-DICHLORO)-BIS[MU-DIMETHYLTIN(IV)]-BIS-[CHLORODIMETHYLTIN(IV)], AND ITS ETHYL HOMOLOG
HARRISON, PG
BEGLEY, MJ
MOLLOY, KC
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 186 (02) : 213 - 236
[3] DISTANNOXANE-CATALYZED ACETALIZATION OF CARBONYLS
OTERA, J
DANOH, N
NOZAKI, H
[J]. TETRAHEDRON, 1992, 48 (08) : 1449 - 1456
[4] DISTANNOXANE-CATALYZED TRANSESTERIFICATION OF 1,N-DIOL DIACETATES - SELECTIVE TRANSFORMATION OF EITHER OF CHEMICALLY EQUIVALENT FUNCTIONAL-GROUPS
OTERA, J
DANOH, N
NOZAKI, H
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (24) : 1742 - 1745
[5] CRYSTAL-STRUCTURES OF ISOPROPYL-SUBSTITUTED AND "TRIMETHYLSILYLMETHYLENE-SUBSTITUTED CHLORO-HYDROXO-TETRAORGANYL-DISTANNOXANES
PUFF, H
BUNG, I
FRIEDRICHS, E
JANSEN, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 254 (01) : 23 - 32
[6] PENTA-COORDINATED MOLECULES .52. HYDROLYSIS PATHWAY LEADING TO THE FORMATION OF NOVEL OXO-BRIDGED AND HALO-BRIDGED TIN(IV) LADDER COMPOUNDS - THE MOLECULAR-STRUCTURE OF THE DIMERIC DISTANNOXANES [PH2(CL)SNOSNPH2(OH)]2.2(CH3)2CO AND [PH2(CL)SNOSNPH2(CL)]2
VOLLANO, JF
DAY, RO
HOLMES, RR
[J]. ORGANOMETALLICS, 1984, 3 (05) : 745 - 750
[7] SN-119 NMR SPECTROSCOPIC STUDY ON TETRAORGANODISTANNOXANES
YANO, T
NAKASHIMA, K
OTERA, J
OKAWARA, R
[J]. ORGANOMETALLICS, 1985, 4 (09) : 1501 - 1503

← 1 →