CHARACTERIZATION BY ELECTROSPRAY-IONIZATION (ESI) MASS-SPECTROMETRY OF AN OLIGOMERIC, ANIONIC THIOMALATO-SILVER(I) COMPLEX SHOWING BIOLOGICAL-ACTIVITY

被引：44

作者：

NOMIYA, K ^{[1
]}

KONDOH, Y ^{[1
]}

NAGANO, H ^{[1
]}

ODA, M ^{[1
]}

机构：

[1] MEIJI MILK PROD CO LTD,MEIJI CELL TECHNOL CTR,ODAWARA,KANAGAWA 250,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 16期

关键词：

D O I：

10.1039/c39950001679

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetrameric anionic species {Na-3[Ag(Htma)](4)}(-) (m/z = 1092.8; H(3)tma = thiomalic acid) is detected by negative-ion electrospray ionization (ESI) mass spectrometry as a stable constituent unit derived from an aqueous solution of the oligomeric thiomalato-silver(I) complex, recently isolated and characterized as {Na[As(Htma)] . 0.5H(2)O}(n) (n = 24-34) 1, which displays antimicrobial activity against selected bacteria, yeast and moulds.

引用

页码：1679 / 1680

页数：2

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