MOSSBAUER-SPECTROSCOPY OF LIQUID SNCL4 SOLUTIONS TRAPPED IN A RIGID MICROEMULSION

被引：6

作者：

BURGER, K

VERTES, A

DEKANY, I

NEMESVETESSY, Z

机构：

[1] EOTVOS LORAND UNIV, NUCL CHEM LAB, H-1364 BUDAPEST 5, HUNGARY

[2] ATTILA JOZSEF UNIV, DEPT COLLOID CHEM, H-6701 SZEGED, HUNGARY

来源：

STRUCTURAL CHEMISTRY | 1991年 / 2卷 / 3-4期

关键词：

D O I：

10.1007/BF00672223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rigid microemulsion was prepared containing submicroscopic droplets of liquid aqueous tin tetrachloride solution. Recoilless gamma-ray resonance absorption (the Mossbauer effect) was achieved in this system, indicating that the organic dispersion medium of the microemulsion behaved as a carrier, enhancing the Debye-Waller factor for the quasi-liquid phase of the system. The Mossbauer spectra reflected the presence of two types of tin(IV) in the cavities of the microemulsion: SnCl4 species situated in the bulk solution and on the cavity wall, respectively.

引用

页码：277 / 280

页数：4

共 7 条

[1] CAPILLARY MOSSBAUER-SPECTROSCOPY (CMS) - A NEW METHOD FOR THE STUDY OF LIQUIDS FIXED IN A SUITABLE CARRIER [J].