STRETCHING VIBRATIONS OF BENZENE IN THE ALGEBRAIC MODEL

被引：57

作者：

IACHELLO, F

OSS, S

机构：

[1] UNIV TRENTO,DIPARTMENTO FIS,I-38050 TRENT,ITALY

[2] IST NAZL FIS NUCL,COLLESATO TRENTO GRP,I-38050 TRENT,ITALY

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 187卷 / 05期

关键词：

D O I：

10.1016/0009-2614(91)80290-E

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We introduce an algebraic model of coupled anharmonic oscillators capable of describing the complete spectrum and intensities of X-Y stretching vibrations of medium size and large polyatomic molecules. We apply this model to the calculation of C-H and C-D stretches of C6H6 and C6D6. The model appears to describe the data accurately.

引用

收藏

页码：500 / 505

页数：6

相关论文

共 21 条

[1] GROUP-THEORY OF THE MORSE OSCILLATOR [J].

ALHASSID, Y ;

IACHELLO, F ;

GURSEY, F .

CHEMICAL PHYSICS LETTERS, 1983, 99 (01) :27-30

[2] GROUP-THEORY APPROACH TO SCATTERING [J].

ALHASSID, Y ;

GURSEY, F ;

IACHELLO, F .

ANNALS OF PHYSICS, 1983, 148 (02) :346-380

[3]

BRADERSEN S, 1956, KGL DANSKE VIDENSKAB, V1, P1

[4] MODEL STRETCHING OVERTONE EIGENVALUES FOR SF6, WF6, AND UF6 [J].

HALONEN, L ;

CHILD, MS .

JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (02) :559-570

[5] LOCAL MODE VIBRATIONS IN BENZENE [J].

HALONEN, L .

CHEMICAL PHYSICS LETTERS, 1982, 87 (03) :221-225

[6] THE OVERTONE SPECTRUM OF ACETYLENE IN THE VIBRON MODEL [J].

HORNOS, J ;

IACHELLO, F .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (10) :5284-5291

[7] VIBRATIONAL-SPECTRA OF LINEAR TRIATOMIC-MOLECULES IN THE VIBRON MODEL [J].

IACHELLO, F ;

OSS, S ;

LEMUS, R .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1991, 146 (01) :56-78

[8] OVERTONE FREQUENCIES AND INTENSITIES OF BENT-XY2 MOLECULES IN THE VIBRON MODEL [J].

IACHELLO, F ;

OSS, S .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1990, 142 (01) :85-107

[9] MODEL OF N-COUPLED ANHARMONIC-OSCILLATORS AND APPLICATIONS TO OCTAHEDRAL MOLECULES [J].

IACHELLO, F ;

OSS, S .

PHYSICAL REVIEW LETTERS, 1991, 66 (23) :2976-2979

[10] ALGEBRAIC APPROACH TO MOLECULAR ROTATION-VIBRATION SPECTRA .1. DIATOMIC-MOLECULES [J].

IACHELLO, F ;

LEVINE, RD .

JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (06) :3046-3055