RESIDUAL DIPOLAR SPLITTINGS IN C-13-MAS NMR ARISING FROM INTERACTIONS WITH CHLORINE NUCLEI

被引：16

作者：

HARRIS, RK ^{[1
]}

SUNNETCIOGLU, MM ^{[1
]}

CAMERON, KS ^{[1
]}

RIDDELL, FG ^{[1
]}

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

MAGNETIC RESONANCE IN CHEMISTRY | 1993年 / 31卷 / 10期

关键词：

SOLID-STATE NMR; C-13; MAGIC-ANGLE SPINNING; RESIDUAL DIPOLAR SPLITTINGS; 2ND-ORDER QUADRUPOLAR EFFECTS; CARBON-CHLORINE INTERACTIONS;

D O I：

10.1002/mrc.1260311016

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Residual dipolar splittings in C-13 cross-polarization magic-angle spinning spectra arising from coupling to chlorine nuclei are reported for the three chloroacetanilide isomers, using several spectrometers. At medium to high magnetic field doublets are seen for C-Cl carbon resonances. Perturbation theory explains the appearance of the spectra qualitatively but is inadequate quantitatively.

引用

页码：963 / 965

页数：3

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