QUANTUM YIELD OF CHLORINE-ATOM FORMATION IN THE PHOTODISSOCIATION OF CHLORINE PEROXIDE (CLOOCL) AT 308 NM

被引：57

作者：

MOLINA, MJ ^{[1
]}

COLUSSI, AJ ^{[1
]}

MOLINA, LT ^{[1
]}

SCHINDLER, RN ^{[1
]}

TSO, TL ^{[1
]}

机构：

[1] CALTECH,JET PROP LAB,PASADENA,CA 91109

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 173卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)85275-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The production of Cl atoms in the laser flash photolysis of ClOOCl at 308 nm has been investigated by time-resolved atomic resonance fluorescence at 235 K. A value of φ = 1.03 ± 0.12 has been obtained for the primary quantum yield based on an absorption cross section ratio σ245/σ308 = 22 for ClOOCl at 245 and 308 nm. © 1990.

引用

页码：310 / 315

页数：6

共 16 条

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