PERHYDROLYSIS OF NERVE AGENT VX

被引：100

作者：

YANG, YC ^{[1
]}

SZAFRANIEC, LL ^{[1
]}

BEAUDRY, WT ^{[1
]}

BUNTON, CA ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA, DEPT CHEM, SANTA BARBARA, CA 93106 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 25期

关键词：

D O I：

10.1021/jo00077a011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The exceedingly toxic nerve agent VX (O-ethyl S-(2-diisopropylamino(ethyl methylphosphonothioate) cannot be detoxified by reaction with hydroxide ion but is rapidly detoxified by perhydrolysis (substitution with HO2-) presumably via an intramolecular oxygen transfer which precludes loss of the ethoxy group.

引用

页码：6964 / 6965

页数：2

共 20 条

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