THE COORDINATION CHEMISTRY OF MIXED PYRIDINE-PHENOL AND PHENANTHROLINE-PHENOL LIGANDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [PDL1CL].(CH2CL2) [HL1=6-(2-HYDROXYPHENYL)-2,2'-BIPYRIDINE]

被引：7

作者：

BARDWELL, D ^{[1
]}

BLACK, D ^{[1
]}

JEFFERY, JC ^{[1
]}

WARD, MD ^{[1
]}

机构：

[1] UNIV BRISTOL,SCH CHEM,CANTOCKS CLOSE,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 13期

关键词：

D O I：

10.1016/S0277-5387(00)87064-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of the N,N,O-terdentate ligands 6-(2-hydroxyphenyl)-2,2'-bipyridine (HL1) and 2-(2-hydroxyphenyl)-1,10-phenanthroline (HL2) with Na2PdCl4.3H2O afforded the complexes [PdL1Cl] and [PdL2Cl]; the crystal structure of [PdL1Cl].(CH2Cl2) shows it to be a square-planar monomer with extensive intramolecular pi-stacking interactions involving the aromatic ligands.

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页码：1577 / 1580

页数：4

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