EVIDENCE FOR ADSORBED SO2 AT THE AQUEOUS AIR INTERFACE

被引：68

作者：

DONALDSON, DJ

GUEST, JA

GOH, MC

机构：

[1] UNIV TORONTO,SCARBOROUGH COLL,TORONTO,ON M5S 1A1,CANADA

[2] UNIV CINCINNATI,DEPT CHEM,CINCINNATI,OH 45221

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 23期

关键词：

D O I：

10.1021/j100023a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present direct experimental evidence for the existence of a surface-bound state of partially hydrated SO2 on water. Surface second harmonic generation (SHG) and static surface tension measurements are used to examine the SO2 surface coverage as a function of its bulk aqueous concentration. The results indicate a Langmuir-type adsorption of SO2 at the air-water interface. These experiments represent the first report of the application of surface SHG techniques to detect gas adsorption onto a liquid surface.

引用

页码：9313 / 9315

页数：3

共 21 条

[1] ADAM NK, 1941, PHYSICS CHEM SURFACE
[2] ADAMSON AW, 1982, PHYSICAL CHEM SURFAC
[3] BRAKER W, 1980, MATHESON GAS DATA BO
[4] OPTICAL 2ND-HARMONIC GENERATION AS A PROBE OF SURFACE-CHEMISTRY
CORN, RM
HIGGINS, DA
[J]. CHEMICAL REVIEWS, 1994, 94 (01) : 107 - 125
[5] EQUILIBRIUM AND DYNAMIC PROCESSES AT INTERFACES BY 2ND HARMONIC AND SUM FREQUENCY GENERATION
EISENTHAL, KB
[J]. ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1992, 43 : 627 - 661
[6] LIQUID INTERFACES
EISENTHAL, KB
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (12) : 636 - 643
[7] Finlayson-Pitts B.J., 1986, ATMOSPHERIC CHEM
[8] THERMODYNAMICS OF SOLUTION OF SO2(G) IN WATER AND OF AQUEOUS SULFUR-DIOXIDE SOLUTIONS
GOLDBERG, RN
PARKER, VB
[J]. JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1985, 90 (05): : 341 - 358
[9] GOLDEN DM, 1994, CHEM ATMOSPHERE ITS, pCH4
[10] GENERAL-CONSIDERATIONS ON OPTICAL 2ND-HARMONIC GENERATION FROM SURFACES AND INTERFACES
GUYOTSIONNEST, P
CHEN, W
SHEN, YR
[J]. PHYSICAL REVIEW B, 1986, 33 (12): : 8254 - 8263

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