A DIARYLHEPTANOID INTERMEDIATE IN THE BIOSYNTHESIS OF PHENYLPHENALENONES IN ANIGOZANTHOS-PREISSII

被引：44

作者：

HOLSCHER, D ^{[1
]}

SCHNEIDER, B ^{[1
]}

机构：

[1] INST PFLANZENBIOCHEM,D-06120 HALLE,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 05期

关键词：

D O I：

10.1039/c39950000525

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The incorporation of 1-phenyl-7-(3,4-dihydroxyphenyl)hepta-1,3-dien-5-one and two molecules of cinnamic acid, respectively, into anigorufone by cultured roots of Anigozanthos preissii provides the first experimental evidence for the biosynthesis of a phenylphenalenone from two C-6-C-3 units via an open chain type diarylheptanoid.

引用

页码：525 / 526

页数：2

共 18 条

[1] SYNTHESIS OF LACHANANTHOCARPONE [9-PHENYL-2,6-DIHYDROXYPHENALEN-1(6)-ONE] BY INTRA-MOLECULAR DIELS-ALDER CYCLIZATION OF A1,7-DIARYLHEPTANOID ORTHO-QUINONE - POSSIBLE BIOSYNTHETIC SIGNIFICANCE OF DIELS-ALDER REACTIONS [J].