THE METAL ALKYL BOND-ENERGY OF THE FE(100) HYDROGEN ETHYL SURFACE COMPLEX

被引：19

作者：

BURKE, ML

MADIX, RJ

机构：

[1] STANFORD UNIV,DEPT CHEM & CHEM ENGN,STANFORD,CA 94305

[2] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 08期

关键词：

D O I：

10.1021/ja00034a002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermochemical cycle has been constructed for the reactions of ethylene on H-presaturated Fe(100); this cycle has been used to accurately determine Fe-C2H5 and Fe-H surface bond energies of 38 +/- 4 and 59.5 +/- 2 kcal/mol, respectively. The Fe-C2H5 bond energy is considerably smaller than that measured in the gas phase. Both values are similar to those expected for mononuclear transition metal complexes, provided that the complex contains a first or second row transition metal and is not sterically crowded.

引用

页码：2780 / 2783

页数：4

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