PLATINUM(II) TRIAMINE COMPLEXES - CIS-[PTCL(NH3)(2)(C10H13N5O5)]NO3.2H2O AND [PTCL(C2H8N2)(C4H6N2)]NO3

被引:8
作者
ARVANITIS, GM
GIBSON, D
EMGE, TJ
BERMAN, HM
机构
[1] HEBREW UNIV JERUSALEM,SCH PHARM,DEPT PHARMACEUT CHEM,IL-91120 JERUSALEM,ISRAEL
[2] RUTGERS STATE UNIV,DEPT CHEM,PISCATAWAY,NJ 08855
关键词
D O I
10.1107/S010827019301073X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structures of cis-diamminechloro(guanosine-N-7)platinum(II) nitrate dihydrate, cis-[PtCl(NH3)(2)(C10H13N5O5)]NO3 .2H(2)O, (I), and chloro(ethylenediamine)(1-methylimidazole-N-3)platinum(II) nitrate, [Pt(C2H8N2)(C4H6N2)Cl]NO3 , [PtCl(en)(1-MeIm)]NO3, (II), were determined by single-crystal X-ray diffraction. The former complex crystallized in the orthorhom bic system and the latter in the monoclinic system. In compound (I), water molecules were found to connect the metal complex with the nitrate counter ions via hydrogen bonding.
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页码:1217 / 1220
页数:4
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