LIGAND-EXCHANGE AND REACTION-MECHANISMS OF FLUORINATED COMPOUNDS

被引：23

作者：

JANZEN, AF

机构：

[1] Department of Chemistry, University of Manitoba, Winnipeg

来源：

COORDINATION CHEMISTRY REVIEWS | 1994年 / 130卷 / 1-2期

关键词：

D O I：

10.1016/0010-8545(94)80009-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The topic of ligand exchange and reaction mechanisms of fluorinated compounds is reviewed, with emphasis on the main group fluorides. Mechanisms are divided into a series of elementary steps of bond formation and bond dissociation, using the coordination model of reaction mechanisms as an organizing principle. Included in this review is an analysis of the stereochemical behavior of pentacoordinated molecules, as well as a discussion of the role of impurities, anionic, cationic, free radical and fluorine-bridged intermediates, and fluoride-induced reactions.

引用

页码：355 / 426

页数：72

共 580 条

[1]

Abe T., 1973, J FLUORINE CHEM, V3, P187

[2] VIBRATIONAL-SPECTRA AND STRUCTURES OF SELENIUM TETRAFLUORIDE AND TELLURIUM TETRAFLUORIDE - INCLUDING A MATRIX-ISOLATION STUDY [J].