LIGAND ENDOR STUDY OF THE TRIGONAL BIPYRAMIDAL COPPER-COMPLEXES, [CU(TREN)NH3](CLO4)(2) AND [CU(TREN)NCS]SCN IN THE POWDER STATE (TREN=TRIS(2-AMINOETHYL)AMINE)

被引：3

作者：

EHSAN, MQ ^{[1
]}

OHBA, Y ^{[1
]}

YAMAUCHI, S ^{[1
]}

IWAIZUMI, M ^{[1
]}

机构：

[1] TOHOKU UNIV, INST CHEM REACT SCI, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 02期

关键词：

D O I：

10.1246/cl.1995.151

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The HFC and NQC constants for all the coordinating atoms of the ligand tren, tris(2-aminoethyl)amine, in the trigonal bipyramidal (tbp) copper complexes [Cu(tren)NH3](ClO4)(2) 1 and [Cu(tren)NCS]SCN 2 have been determined from the angle selected ENDOR study in the powder state. The spin distribution and the metal ligand bonding nature in the copper (tbp) complexes are discussed.

引用

页码：151 / 152

页数：2

共 10 条

[1] CRYSTAL-STRUCTURE AND ELECTRONIC-PROPERTIES OF AMMINE[TRIS(2-AMINOETHYL)AMINE]COPPER(II) DIPERCHLORATE AND POTASSIUM PENTA-AMMINECOPPER(II) TRIS(HEXAFLUOROPHOSPHATE) [J].

DUGGAN, M ;

RAY, N ;

HATHAWAY, B ;

TOMLINSON, G ;

BRINT, P ;

PELIN, K .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (08) :1342-1348

[2] CRYSTAL STRUCTURE OF BETA,BETA',BETA''-TRIAMINOTRIETHYLAMINEISOTHIOCYANATOCOPPER(2) THIOCYANATE [J].

JAIN, PC ;

LINGAFEL.EC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (24) :6131-&

[3]

Jiang F., 1993, INORG CHEM, V32, P2576

[4] ENDOR STUDIES OF [N,N'-ETHYLENEBIS(SALICYLIDENIMINATO)]COPPER(II) IN [N,N'-ETHYLENEBIS(SALICYLIDENIMINATO)]NICKEL(II) SINGLE-CRYSTALS [J].

KITA, S ;

HASHIMOTO, M ;

IWAIZUMI, M .

INORGANIC CHEMISTRY, 1979, 18 (12) :3432-3438

[5]

LUCKEN EAC, 1969, NUCLEAR QUADRUPOLE 2, V1

[6] HYPERFINE INTERACTIONS OF COORDINATING NITROGENS IN THE COPPER(II) COMPLEXES HAVING A N2S2 DONOR SET AND BLUE COPPER PROTEINS [J].

MIYAMOTO, R ;

OHBA, Y ;

IWAIZUMI, M .

INORGANIC CHEMISTRY, 1990, 29 (17) :3234-3238

[7]

MIYAMOTO R, 1991, INORG CHEM, V31, P3138

[8] LIGAND ENDOR OF METAL COMPLEXES IN POWDERS [J].

RIST, GH ;

HYDE, JS .

JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (09) :4633-&

[9] 5-COORDINATE NICKEL(2) COMPLEXES WITH NITROGENPHOSPHORUS AND NITROGEN-ARSENIC TETRADENTATE LIGANDS [J].

SACCONI, L ;

BERTINI, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (09) :2235-&

[10]

Schweiger A., 1982, STRUCT BONDING BERLI, V51, P1

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