A NEW CARBON HYDROGEN-BOND ACTIVATION REACTION - STEREOSPECIFIC ABSTRACTION OF VINYLIC PROTONS FROM RHENIUM ALKENE COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(H2C=CHR)]+BF4-BY THE BASE TERT-BUO-K+

被引：22

作者：

PENG, TS

GLADYSZ, JA

机构：

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 11期

关键词：

D O I：

10.1021/om00161a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title reaction gives the vinyl complexes (η5-C5H5)Re(NO)(PPh3(CH=CHR) for R = CH(CH3)2 and C6H5; deuterium labeling and NMR experiments show that only one of the two geminal alkene ligand protons is abstracted.

引用

页码：2884 / 2886

页数：3

共 11 条

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