CARBOHYDRATE SEPARATION BY LIGAND-EXCHANGE LIQUID-CHROMATOGRAPHY - CORRELATION BETWEEN THE FORMATION OF SUGAR CATION COMPLEXES AND THE ELUTION ORDER

被引：47

作者：

CARUEL, H ^{[1
]}

RIGAL, L ^{[1
]}

GASET, A ^{[1
]}

机构：

[1] ECOLE NATL SUPER CHIM TOULOUSE,CATAR,CHIM AGRORESSOURCES LAB,118 ROUTE NARBONNE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF CHROMATOGRAPHY | 1991年 / 558卷 / 01期

关键词：

D O I：

10.1016/0021-9673(91)80114-V

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Carbohydrate separation (hexoses, pentoses and corresponding polyols) was studied by liquid chromatography using ligand exchange on cation-exchange resin column with water as eluent. Seven cations (Ca2+, Sr2+ , Ba2+, Pb2+, Y3+, La3+ and Pr3+) were tested. The carbohydrate elution order is considered in connection with the complexing sites likely to be involved for each sugar or polyol molecule and with the exclusion processes.

引用

页码：89 / 104

页数：16

共 31 条

[1]

ANGUAL SJ, 1967, CARBOHYD RES, V4, P269

[2] COMPLEXES OF CARBOHYDRATES WITH METAL CATIONS .4. CYCLITOLS [J].

ANGYAL, SJ ;

HICKMAN, RJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1975, 28 (06) :1279-1287

[3] COMPLEXES OF CARBOHYDRATES WITH METAL CATION .10. SEPARATION OF SUGARS AND OF POLYOLS ON CATION-EXCHANGE RESINS IN THE CALCIUM FORM [J].

ANGYAL, SJ ;

BETHELL, GS ;

BEVERIDGE, RJ .

CARBOHYDRATE RESEARCH, 1979, 73 (AUG) :9-18

[4] EQUILIBRIA BETWEEN PYRANOSES AND FURANOSES .2. ALDOSES [J].

ANGYAL, SJ ;

PICKLES, VA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1972, 25 (08) :1695-&

[5] COMPOSITION AND CONFORMATION OF SUGARS IN SOLUTION [J].

ANGYAL, SJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (03) :157-&

[6] COMPLEXES OF CARBOHYDRATES WITH METAL CATIONS .1. DETERMINATION OF EXTENT OF COMPLEXING BY NMR-SPECTROSCOPY [J].

ANGYAL, SJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1972, 25 (09) :1957-&

[7] COMPLEXES OF CARBOHYDRATES WITH METAL-CATIONS .14. SEPARATION OF SUGARS AND ALDITOLS BY MEANS OF THEIR LANTHANUM COMPLEXES [J].

ANGYAL, SJ ;

MILLS, JA .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1985, 38 (08) :1279-1285

[8] CONFORMATIONAL ANALYSIS IN CARBOHYDRATE CHEMISTRY .I. CONFORMATIONAL FREE ENERGIES . CONFORMATIONS AND ALPHA - BETA RATIOS OF ALDOPYRANOSES IN AQUEOUS SOLUTION [J].

ANGYAL, SJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1968, 21 (11) :2737-&

[9]

ANGYAL SJ, 1974, TETRAHEDRON, V30, P195

[10]

ANGYAL SJ, 1974, AUST J CHEM, V37, P1447

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