ELASTICITY OF POLYMER GELS - EFFECT OF SOLVENT QUALITY ON THE SHEAR MODULUS OF POLY(VINYL ACETATE) NETWORKS

被引：3

作者：

HORKAY, F ^{[1
]}

ZRINYI, M ^{[1
]}

GEISSLER, E ^{[1
]}

HECHT, AM ^{[1
]}

机构：

[1] UNIV GRENOBLE 1, SPECT PHYS LAB, CNRS, F-38402 ST MARTIN DHERES, FRANCE

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1990年 / 40卷

关键词：

D O I：

10.1002/masy.19900400120

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The dependence of the shear modulus and of the swelling equilibrium concentration of polyvinylacetate gel homologues in equilibrium with excess isopropyl alcohol is investigated in the temperature range 30 less-than-or-equal-to T less-than-or-equal-to 70-degrees-C. At the theta temperature (T = 52-degrees-C) the volume elastic modulus was also determined and compared with the shear modulus. The results are interpreted in terms of a free-energy function derived on the basis of the network unfolding hypothesis.

引用

页码：195 / 202

页数：8

共 21 条

[1]

[Anonymous], 1979, SCALING CONCEPTS POL

[2] SOME COMMENTS ON THE SWELLING OF POLYMERIC NETWORKS IN RELATION TO THEIR STRUCTURE [J].

BASTIDE, J ;

PICOT, C ;

CANDAU, S .

JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1981, B19 (01) :13-34

[3] CHARACTERIZATION OF POLYSTYRENE NETWORKS BY SMALL-ANGLE NEUTRON-SCATTERING [J].

BENOIT, H ;

DECKER, D ;

DUPLESSIX, R ;

PICOT, C ;

REMPP, P .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1976, 14 (12) :2119-2128

[4] VOLUME DEPENDENCE OF THE ELASTIC EQUATION OF STATE .2. SOLUTION-CURED POLY(DIMETHYLSILOXANE) [J].

BROTZMAN, RW ;

EICHINGER, BE .

MACROMOLECULES, 1981, 14 (05) :1445-1448

[5] SWELLING OF MODEL POLY(DIMETHYLSILOXANE) NETWORKS [J].

BROTZMAN, RW ;

EICHINGER, BE .

MACROMOLECULES, 1983, 16 (07) :1131-1136

[6] VOLUME DEPENDENCE OF THE ELASTIC EQUATION OF STATE .3. BULK-CURED POLY(DIMETHYLSILOXANE) [J].

BROTZMAN, RW ;

EICHINGER, BE .

MACROMOLECULES, 1982, 15 (02) :531-535

[7]

CANDAU S, 1982, ADV POLYM SCI, V44, P27

[8]

Flory P. J., 1953, PRINCIPLES POLYM CHE

[9] THEORY OF ELASTICITY OF POLYMER NETWORKS .3. [J].

FLORY, PJ ;

ERMAN, B .

MACROMOLECULES, 1982, 15 (03) :800-806

[10] RADIUS OF GYRATION IN ANISOTROPICALLY SWOLLEN GELS [J].

GEISSLER, E ;

DUPLESSIX, R ;

HECHT, AM .

MACROMOLECULES, 1983, 16 (04) :712-713

← 1 2 3 →