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CHARACTERISTICS OF AN INDUCTIVELY-COUPLED ARGON PLASMA OPERATING WITH ORGANIC AEROSOLS .1. SPECTRAL AND SPATIAL OBSERVATIONS
被引:45
作者:
WEIR, DG
[1
]
BLADES, MW
[1
]
机构:
[1] UNIV BRITISH COLUMBIA,DEPT CHEM,VANCOUVER,BC,CANADA
关键词:
INDUCTIVELY COUPLED ARGON PLASMA;
ORGANIC SOLVENT;
SOLVENT PLASMA LOAD;
THERMAL PINCH;
D O I:
10.1039/ja9940901311
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
The effect of solvent and solvent load on the background spectra and visual features obtained from an inductively coupled argon plasma have been recorded. An experimental system for making these measurements is described. The solvents studied were water, methanol and chloroform, at solvent loads corresponding to the maximum and minimum obtainable. The most conspicuous features observed were emission atomic carbon, diatomic carbon and cyanide. A thermal pinch created by the introduction of organic solvents and a recirculation eddy at the base of the torch have been characterized.
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页码:1311 / 1322
页数:12
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