THERMAL-DECOMPOSITION OF MIXED-CRYSTALS NIXMN3-X(C2O4)3.6H2O

被引:16
作者
TOPFER, J
JUNG, J
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D O I
10.1016/0040-6031(92)85172-R
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O414.1 [热力学];
学科分类号
摘要
The preparation and properties of the mixed crystal series NixMn3-x(C2O4)3.6H2O are described. The thermal decomposition of these compounds was observed by thermal analysis. The decomposition products of the compositions with 0.5 < x < 2 in the range 350-400-degrees-C are defect spinel phases NixMn3-x square 3-delta/4O4+delta. The composition of the products is discussed in relation to dependence on temperature and oxygen pressure.
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页码:281 / 289
页数:9
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