EXTENSIVE HIGH-RESOLUTION REVERSE 2D NMR ANALYSIS FOR THE STRUCTURAL ELUCIDATION OF PROCYANIDIN OLIGOMERS

被引:65
作者
BALAS, L
VERCAUTEREN, J
机构
[1] Laboratoire de Pharmacognosie, Université de Bordeaux II, Bordeaux, 33076
关键词
2D NMR; H-1; NMR; C-13; STRUCTURAL ANALYSIS; PROANTHOCYANIDINS; CATECHIN DIMERS; TANNINS;
D O I
10.1002/mrc.1260320703
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The structures of the procyanidin dimers catechin-(4 alpha-8)-catechin and catechin-(4 alpha-6)-catechin were proved by spectroscopic means. To distinguish between the two possible interflavanoid linkages, it is necessary to assign all the quaternary aromatic carbon signals. How these assignments can be made through two-dimensional NMR spectroscopy is described.
引用
收藏
页码:386 / 393
页数:8
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