Selective epoxidation of alpha-isophorone with mesoporous titania-silica aerogels and tert-butyl hydroperoxide

被引:19
作者
Hutter, R [1 ]
Mallat, T [1 ]
Baiker, A [1 ]
机构
[1] ETH ZURICH,DEPT CHEM ENGN & IND CHEM,CH-8092 ZURICH,SWITZERLAND
关键词
D O I
10.1039/C39950002487
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amorphous, mesoporous TiO2-SiO2 mixed oxides, synthesised using a sol-gel process followed by extraction with supercritical CO2, show high selectivities (98%) in the heterogeneous epoxidation of alpha-isophorone in ethylbenzene at 60 degrees C.
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页码:2487 / 2488
页数:2
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