REACTIVITY OF ALLYL-ZINC (AND COPPER) REAGENTS TOWARDS ALLENIC ETHERS AND ALPHA-METALATED ALLENIC ETHERS

被引:11
作者
NORMANT, JF
QUIRION, JC
MASUDA, Y
ALEXAKIS, A
机构
[1] Laboratoire de Chimie, Organoéléments assoié au CNRS, Université P. et M. Curie Tour 44-45, F-75252 Paris Cedex 05
关键词
D O I
10.1016/0040-4039(90)80172-I
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Allylzinc (copper) reagents add to alkoxyallenes in a regioselective way, leading to β-aikoxy vinyl metals. Allyl zinc derivatives react with α - lithoialkoxyallenes to generate regioselectively metallated β-allene-enes. © 1990.
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页码:2879 / 2882
页数:4
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