ENANTIOSELECTIVE CATALYSIS .81. OPTICALLY-ACTIVE 2-LAYER PHOSPHINES

被引:26
作者
BRUNNER, H
FURST, J
ZIEGLER, J
机构
[1] Institut für Anorganische Chemie, Universität Regensburg, W-8400 Regensburg
关键词
D O I
10.1016/0022-328X(93)83227-M
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two-layer phosphines were synthesized by reaction of optically active bromotolyl and bromoxylyl derivates with PCl3 and Cl2P-CH2-CH2-PCl2, respectively. The optically active bromotolyl and bromoxylyl ethers and amines were obtained from the corresponding bromo(bromomethyl)arenes and the optically active alcohols and amines.
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页码:87 / 94
页数:8
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